Dipole-dipole forces occur when the positive part of a polar molecule is attracted to the an unfavorable part that a polar molecule. In a nonpolar molecule, there might still be polar bonds, it"s simply that the dipoles publication each various other out. Therefore why can"t there be dipole-dipole forces between nonpolar molecules through polar bonds? There room still hopeful and negative parts the the molecule, therefore there deserve to be attractions between them.

For example, in $ceCO2$, there are an adverse areas close to the oxygens and positive areas near the carbon.

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Short answer: over there are numerous electrostatic interactions between two non-polar molecules.

Beyond monopole (full charges) and permanent dipole moment (polar molecules), there is a complete multipole development for the electrostatic potential around any molecule. (This is technically true for atoms and ions too, however higher-order terms are really only helpful for molecules.)

So there space electrostatic potential energy interaction terms for charge-dipole, dipole-dipole, dipole-quadrupole, quadrupole-quadrupole, etc.

These terms are crucial - the quadrupole-quadrupole interactions dictate the orientation of the benzene dimer and also $ceCO2$ dimer in her example.1

The difficulty is that most of this interactions dice off very quickly. The quadrupole-quadrupole term is:1

$$E(r)=frac-Theta_1Theta_24piepsilon_0r^5 imesGamma( heta_1, heta_2,phi)$$

So roughly $1/r^5$, contrasted to $1/r^3$ because that dipole-dipole interactions, or $1/r^6$ for dispersion pressures like induced-dipoles.

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When together molecules room close, the quadrupole moment (and various other multipole electrostatic terms) have the right to dictate packing and also distances, however are no as solid or as long-range together dipole-dipole or charge interactions.